Modelling of Irreversible Homogeneous Reaction on Finite Diffusion Layers
نویسندگان
چکیده
The mathematical model proposed by Chapman and Antano (Electrochimica Acta, 56 (2010), 128–132) for the catalytic electrochemical–chemical (EC’) processes in an irreversible second-order homogeneous reaction a microelectrode is discussed. mass-transfer boundary layer neighbouring electrode can contribute to electrode’s measured AC impedance. This be used analyse membrane-transport studies other instances of ionic transport semiconductors materials. Two efficient easily accessible analytical techniques, AGM DTM, were solve steady-state non-linear diffusion equation’s infinite layers. Herein, we present generalized approximate solution solute, product, reactant concentrations current small experimental values kinetic parameters. Using Matlab/Scilab program, also derive numerical this problem. comparison numerical/computational results reveals satisfactory level agreement.
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ژورنال
عنوان ژورنال: Electrochem
سال: 2022
ISSN: ['2673-3293']
DOI: https://doi.org/10.3390/electrochem3030033